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Abstract Geometrically frustrated kagome lattices are raising as novel platforms to engineer correlated topological electron flat bands that are prominent to electronic instabilities. Here, we demonstrate a phonon softening at thekz = πplane in ScV6Sn6. The low energy longitudinal phonon collapses at ~98 K andq = $$\frac{1}{3}\frac{1}{3}\frac{1}{2}$$ due to the electron-phonon interaction, without the emergence of long-range charge order which sets in at a different propagation vectorqCDW = $$\frac{1}{3}\frac{1}{3}\frac{1}{3}$$ . Theoretical calculations corroborate the experimental finding to indicate that the leading instability is located at$$\frac{1}{3}\frac{1}{3}\frac{1}{2}$$ of a rather flat mode. We relate the phonon renormalization to the orbital-resolved susceptibility of the trigonal Sn atoms and explain the approximately flat phonon dispersion. Our data report the first example of the collapse of a kagome bosonic mode and promote the 166 compounds of kagomes as primary candidates to explore correlated flat phonon-topological flat electron physics.more » « less
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Zhang, Yi C.; Lee, David Y.; Hipps, K. W. (, The Journal of Physical Chemistry C)
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Han, Guanqun; Yan, Tao; Zhang, Wei; Zhang, Yi C.; Lee, David Y.; Cao, Zhi; Sun, Yujie (, ACS Catalysis)
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